It's great to see that finally most discharge ink manufacturers are offering Pantone starter formulas. When I first started you were completely on your own. Heres how we started off. Below is a pic of Sericl GS blue both with 6% activator. The seies of dots on the left is the exact same color cut in half with binder. We would continue to cut these single pigmented colors with different amounts of binder and strike these off to be later assembled into formula notebooks. Very quickly we assembled 60 or more single pigmented colors. (BTW for best results and cleanest colors stay away from white ink or PCs in your formulas)
Next we began to make secondary and tertiary colors by combining pigments (or inks) You'll be suprised how many colors can be made with simply combining two hues (IE Purple plus Orange make great browns)