Opportunity is missed by most people because it is dressed in overalls and looks like work. - Thomas Edison
Sounds like you cured the white--if the white isn't washing off but the gold is. They aren't cracking?
I have overprinted old prints and had the new prints stick just fine.That said, comm0on thought and standard procedure is to only barely gel the underbase for better adhesion. Perhaps the gold true metallic needs even more "tooth" than other inks, but I think that more likely, the gold did not fully cure.Metallics and shimmers require more heat or dwell due to their refectivity. Especially if the problem started with the first wash, that's my vote.btw, an underbase is usually not p/f/p, since you aren't going for a really solid ink layer, just white enough to cover the black and help the ink pop. If you are going to that much work making a white underbase, you may want to experiment just p-f-p with a gold shimmer only through a 110 or 120.
I hope the ink techs can chime in.If the underbase is fully cured, and you print a top layer on it,would you require "re-melting" the underbase layer to bond with the top layer?I could see getting to curing temps, especially measured at the top, and notbonding with the base.I'm with Andy in not having cured base/top layer adhesion problems, but we generallytend to shoot for gelling the base only, and quite a bit towards "over" cure then under.
Your pallets retain heat and less heat is required as you go along. I'll bet your under base was cured.